Anionexchange separation of iron, cobalt and nickelAbstract. From 90% acetone10% 6 M hydrochloric acid medium, cobalt and nickel are strongly adsorbed on the anionexchange resin Dowex IX8; iron is not adsorbed and can thus be separated from cobalt and nickel. Cobalt and nickel are then separated by elution with 70% acetone30% 2 M hydrochloric acid; nickelCited by 23Determination of nickel, manganese, cobalt, and iron into an anionexchange column containing Dowexl. The nickel and manganese, with chro mium and some other elements. are collected in t he first fraction by elution with 9 N hydro chloric acid. Cobalt is collected in a second fraction by elution wit h 4 N hydrochloric acid, and iron in a third by elution with 1 N hydrochloric
Separation of coexisting nickel, cobalt, and iron ions from acidic and ammoniacal solutions on stannic arsenate silica gel G (101 w/w) mixed sorbent layers impregnated with 0.2M trin
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An anion exchange technique has been developed for the determination of iron, nickel, cobalt and zinc in a ferrite type material. The constituents are separated by utilizing the difference in the adsorption of the chloride complexes on a strongly basic anion exchange resin.
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"Gradient Elution in Ion Chromatography Anion Exchange With Conductivity Detection", Dionex, Jan. 1987, pp. 17. "The Metsep Process For The Separation And Recovery Of Zinc, Iron, And Hydrochloric Acid From Spent Pickle Liquors", Tunley, Journal Of The South African Institute Of Mining And Metallurgy, May 1976, pp. 422427.
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Hydrometallurgy 61223227. KyungHo P, Debasish M (2006). Process for Cobalt separation and recovery in the presence of nickel from sulphate solutions by Cyanex 272. Met. Mater. Int. 12441446. Lenhard Z (2008). Extraction and separation of Cobalt and Nickel with extractants Cyanex 302, Cyanex 272 and their mixture. Kem. Ind. 57417423.
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determined by anion exchange separation and suppressed conductivity detection. Keywords Ion chromatography, IC, Dionex Iron, both ferric (Fe 3 +) and ferrous (Fe 2), divalent cations of copper, nickel, zinc, cobalt, cadmium, and manganese.
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4 One of the drawbacks of using Cyanex 272 for separation of nickel and cobalt in pregnant leach solution of laterite ore is its low selectivity to iron and magnesium. Separation of Ni and Co can
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"Gradient Elution in Ion Chromatography Anion Exchange With Conductivity Detection", Dionex, Jan. 1987, pp. 17. "The Metsep Process For The Separation And Recovery Of Zinc, Iron, And Hydrochloric Acid From Spent Pickle Liquors", Tunley, Journal Of The South African Institute Of Mining And Metallurgy, May 1976, pp. 422427.
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The separation and determination of nickel, chromium, cobalt, iron, titanium, tungsten, molybdenum, niobium and tantalum in a high temperature alloy by anionexchange Author links open overlay panel D.H. Wilkins
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systems. A suitable separation of iron, cobalt, and nickel, and of iron, cobalt, nickel, copper, and zinc using anion exchange resin with a methanolic eluent containing a low concentration of hydrochloric acid was devised. Berg and Truemper (18) report the separation of zinc(II), cadmium(II),
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Aqueous solutions containing nickel can be purified of metals capable of forming anionic complex chlorides, particularly, iron and cobalt, by raising the chloride content of the solution to from 2N to 6N by adding a completely dissociated salt of hydrochloric acid followed by contacting the solution with an anion exchange resin at a temperature above 20° C.
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MiniColumn IonExchange Separation and Atomic Absorption Quantitation of Nickel, Cobalt, and Iron An Undergraduate Quantitative Analysis Experiment. Anderson, James L.; And Others. Journal of Chemical Education, v57 n7 p52122 Jul 1980.
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The present invention is related to a hydrometallurgical process to produce nickel as hydroxide, oxide or cathode and produce cobalt preferably as sulfides. The present invention is particularly adequate to process eluate containing nickel and cobalt. Eluates are solutions obtained from elution of ionic exchange resins, loaded (charged) in the RIP (resininpulp) process of ionic exchange, to
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Separation of nickel from cobalt using electrodialysis in the presence of EDTA. Preparation and characterization of iron salt embedded electrodialysis AnalcimeC zeolite clay composite membrane. By Manoj Kumar. Ion Exchange Membranes.
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exchange, (2) Separation of cobalt and nickel, and {3) Thiocyanate complexeso IonExchange Ionexchange is not a recent devel~pment but has been familiar to man as a .phenomena for centuries. The early researchers worked only with naturally occuring materials which exhibited ion
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periodic chart showing the anionexchange behavior of the elements in hydrochloric acid had been prepared (101). Mil ler and Hunter (63) have separated rhenium from aluminum and magnesium using this method. Helwig et al. (30) separated iron from cobalt, zinc and nickel. A large number of specif
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Aqueous solutions containing nickel can be purified of metals capable of forming anionic complex chlorides, particularly, iron and cobalt, by raising the chloride content of the solution to from 2N to 6N by adding a completely dissociated salt of hydrochloric acid followed by contacting the solution with an anion exchange resin at a temperature above 20* C.
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An anionexchange method has been developed for the separation of cobalt from nickel, based on the observation that from a malonic acid solution containing sodium nitrite, cobalt is preferentially adsorbed by the exchanger but nickel passes through. The cobalt is eluted with 2M ammonium chloride in dilute ammonia solution. Prom an ammonium malonate solution containing chloride and nitrate, cobalt is quantitatively
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I MiniColumn lonExchange Separation James L. Anderson' James G r o~~~. hs~ a n d Darryl Frick I and Atomic Absorption Quantitation of North Dakota State University Fargo, N~ 58105 Nickel, Cobalt, and Iron An undergraduate quantitative analysis experiment T h e facile ionexchange chromatographic separation of Also needed are numerous firstrow transition metal ions based on differential 2 ml
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Separation of coexisting nickel, cobalt, and iron ions from acidic and ammoniacal solutions on stannic arsenate silica gel G (101 w/w) mixed sorbent layers impregnated with 0.2M trin
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The separation of cobalt from nickel by anion exchange chromatography Kauffman, George B.; Adams, Matthew L. Abstract. Publication Journal of Chemical Education. Pub Date February 1989 DOI 10.1021/ed066p166 Bibcode 1989JChEd..66..166K full text sources
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Brine/HCI . Iron is normally considered as a divalent or trivalent cation that would be easily picked up by standard cation exchange resins, including AmberSep G26 H Resin. While this is true, one of the most useful applications of ion exchange for iron removal employs anion exchange resin such as AmberSep 21K XLT Resin to capture Fe 3+ (ferric) ions as an anionic complex.
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A detailed study was made of the adsorption of titanium, zirconium, niobium, tantalum, molybdenum, and tungsten on the anionexchange resin, De Acidite FF, from solutions containing mixtures of two or more of hydrofluoric acid, hydrochloric acid, ammonium fluoride, and ammonium chloride, with a view to obtaining a separation scheme for these elements that could be completed within 5 hours.
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To investigate the possibility of separation of metal ions in nitrite medium by anion exchange, adsorption and elution behavior of the three typical transition metals of Co(II), Ni(II) and Cu(II) in nitrite solution with a commercial anion exchanger, Amberlite IRA900 and a novel silicabased anion exchanger, AR01 with fine particle size has been studied.
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for high separation and concentration factors. INORGANIC COMPOUND SCREENING TESTS Thirtythree inorganic compounds were screened for ionexchange activity (1) The hydrous oxides of titanium, iron, zirconium, and tin, (2) the ferrocyanides of chromium, manganese, iron, cobalt, nickel, copper, zinc, cadmium, and lead,
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Separation of nickel from cobalt using electrodialysis in the presence of EDTA. Preparation and characterization of iron salt embedded electrodialysis AnalcimeC zeolite clay composite membrane. By Manoj Kumar. Ion Exchange Membranes.
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A detailed study was made of the adsorption of titanium, zirconium, niobium, tantalum, molybdenum, and tungsten on the anionexchange resin, De Acidite FF, from solutions containing mixtures of two or more of hydrofluoric acid, hydrochloric acid, ammonium fluoride, and ammonium chloride, with a view to obtaining a separation scheme for these elements that could be completed within 5 hours.
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Separation of Iron, Nickel, and Cobalt from Sulphated Leach Liquor of Low Nickel Lateritic Oxide Ore January 2004 Separation Science and Technology 39(2)413429
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An online mini anionexchange chromatographic separation and detection of synthetic Ni(II) and Co(II) sample mixtures was developed. The separation column made use of a tygon tubing with an internal diameter of 1.25 mm packed with anionexchange resin to a length of 25 cm (GLL column) as optimized in the previous study (Lim, G. L. 2004).
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These two effect lead to selective removal of cobalt ion by 371. the act of cation exchange membrane with the help of the cation [3] A.J. Chaudhary, J.D. Donaldson, S.M. Grimes, N.G. Yasri, Separation of nickel from cobalt using electrodialysis in the presence
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Authors Mirza, M Y Publication Date Mon Jan 01 EST 1973 Research Org. Pakistan Inst. of Nuclear Science and Technology, Rawalpindi. Isotope Production Div.
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